expansion chambers have basically one reasons for being.
one to prevent as CO2 entering the gun in liquid form. This means that you will not freeze your gun and have a chance of damaging it. As it has been duely pointed out if the gas enters in liquid form it can expand and damage the marker. Also, in theory, if the gas is expanded the flow of gas will be the same resulting in more constant shots which, in theroy will help your aiming, also the xchambers make your gas last longer, or so they say.