Yes you can..but...it's iffy, because you are then able to fill a bottle, to 4500 psi, that is only designed to take 3000 psi...which is a just the weensiest bit dangerous.
The 4500 reg, wont vent excess pressure...so...the bottle could fail, the threads on the bottle could fail...so either, it blows up in your face, or shoots off and does nasty things to anything in its way.
In short...I wouldnt...